according to US Regulation 29 CFR 1910.1200 and the Canadian HPA Fresh Water Filter Cleaner Version 1.2 Revision Date 2019.02.25 Print Date 2019.11.04 SECTION 1. IDENTIFICATION Product name : Fresh Water Filter Cleaner Manufacturer or supplier's details Company : Arch Chemicals, Inc. 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States of America (USA) E-mail address : sds@lonza.com Emergency telephone number : In case of emergency call CHEMTREC US: 1-800-424-9300, CHEMTREC WORLD-WIDE: +1-703-527-3887. Recommended use of the chemical and restrictions on use Recommended use : Cleansing agents, acidic. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin irritation : Category 2 Serious eye damage : Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H315 Causes skin irritation. H318 Causes serious eye damage. Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P402 + P404 Store in a dry place. Store in a closed container. P410 + P403 Protect from sunlight. Store in a well-ventilated place. Disposal: P501 Dispose of contents/container in accordance with local regu- lation. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Hazardous components Chemical name / Synonyms CAS-No. Concentration (% w/w) Sodium hydrogensulphate 7681-38-1 80 - 85 Citric acid 77-92-9 5 - 15 Sodium dodecylbenzenesulfonate 25155-30-0 0 - 2 SECTION 4. FIRST AID MEASURES If inhaled : IF INHALED: Remove individual to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops. If not breathing, give artificial respiration. Call for medical assistance. In case of skin contact : IF ON SKIN: Immediately flush skin with plenty of water for 15 minutes. If clothing comes in contact with the product, the clothing should be removed immediately and laundered before re-use. Seek medical attention. In case of eye contact : IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical attention immediately. If swallowed : IF SWALLOWED: Call a physician immediately. DO NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person. Most important symptoms and ef- fects, both acute and delayed : None known. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Specific hazards during firefighting : Material will not ignite or burn. Further information : Use water spray to cool unopened containers. In case of fire, use normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing appa- ratus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency proce- dures : Additional protective clothing must be worn to prevent person- al contact with this material. Those items include but are not limited to boots, impervious gloves, hard hat, splash-proof goggles, impervious clothing, i.e., chemically impermeable suit, self-contained breathing apparatus. Prevent further leakage or spillage if safe to do so. Use personal protective equipment as required. Evacuate personnel to safe areas. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for contain- ment and cleaning up : Sweep up and shovel into suitable containers for disposal. Avoid dust formation. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Conditions for safe storage : Store in a cool dry place. Keep out of reach of children. Materials to avoid : Keep away from metals. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters We are not aware of any national exposure limit. Contains no substances with occupational exposure limit values. Engineering measures : Local exhaust ventilation is recommended if significant dust- ing occurs. Otherwise use general exhaust ventilation. Personal protective equipment Respiratory protection : If dusting occurs, wear a NIOSH approved respirator. Wear a NIOSH approved N95 respirator. Hand protection Remarks : Avoid contact with skin. Impervious gloves Eye protection : Chemical resistant goggles must be worn. Skin and body protection : Impervious clothing butyl-rubber Neoprene Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : granular Colour : purple Odour : slight Odour Threshold : no data available pH : < 1.0 Concentration: 10 g/l (as aqueous solution) Melting point/freezing point : Not applicable Boiling point/boiling range : 219.9 °F / 104.4 °C Flash point : no data available Evaporation rate : Not applicable Flammability (solid, gas) : Product is not known to be flammable, combustible, pyrophor- ic or explosive. Flammability (liquids) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : no data available Relative vapour density : Not applicable Relative density : 1.30 (68 °F / 20 °C) Bulk density : no data available Water solubility : 300 g/l (68 °F / 20 °C) Partition coefficient: n-octanol/water : no data available Auto-ignition temperature : no data available Decomposition temperature : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under normal conditions. Conditions to avoid : Heat Incompatible materials : Oxidizing agents Cyanides Sulphides Bases Hazardous decomposition products : Sulphur oxides Other hazardous decomposition products may be formed. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of expo- sure : Ingestion Eyes Skin Inhalation Acute toxicity Acute oral toxicity : LD50: estimated > 3,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): estimated > 2,000 mg/kg Skin corrosion/irritation Remarks: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION. WET MATERIAL CAUSES SKIN BURNS. Serious eye damage/eye irritation Result: Corrosive to eyes Respiratory or skin sensitisation Remarks: Not believed to be sensitising to skin. Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcino- gen by NTP. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcin- ogen by ACGIH. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Components: Citric acid: Partition coefficient: n-octanol/water : log Pow: -1.72 (20 °C) Method: OECD Test Guideline 107 Mobility in soil no data available Other adverse effects Ozone-Depletion Potential : Regulation: US. EPA Clean Air Act (CAA) Section 602 Ozone- Depleting Substances (40 CFR 82, Subpt. A, App A & B) Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No data for product. Individual constituents are as follows: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste Code : LONZA-N09.00602550 Waste from residues : If this product becomes a waste, it DOES NOT meet the crite- ria of a hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D. SECTION 14. TRANSPORT INFORMATION DOT : Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable : TDG Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable IATA Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable IMDG Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable : ADR Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable : RID Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable Special precautions for user : none Transport in bulk according to An- nex II of MARPOL 73/78 and the IBC Code : Not applicable SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium dodecylbenzenesulfonate 25155-30-0 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Acci- dental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Inter- mediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: Components CAS-No. Component RQ (lbs) Sodium dodecylbenzenesulfonate 25155-30-0 1000 The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A: Components CAS-No. Concentration Sodium dodecylbenzenesulfonate 25155-30-0 0 - 2 % This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know Pennsylvania Right To Know Components CAS-No. Sodium hydrogensulphate 7681-38-1 Citric acid 77-92-9 Sodium sulphate 7757-82-6 New Jersey Right To Know Components CAS-No. Sodium hydrogensulphate 7681-38-1 Citric acid 77-92-9 Sodium sulphate 7757-82-6 Sodium dodecylbenzenesulfonate 25155-30-0 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI Canadian National Pollutant Release Inventory (NPRI): No component is listed on NPRI. The components of this product are reported in the following inventories: TSCA : The components of this product are listed on the TSCA Inven- tory of Existing Chemical Substances. SECTION 16. OTHER INFORMATION Full text of other abbreviations AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materi- als; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substanc- es (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan- gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Ja- pan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Pro- tection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and De- velopment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumula- tive and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self- Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative 1 Revision Date : 2019.02.25 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Date format : yyyy/mm/dd US / EN