according to US Regulation 29 CFR 1910.1200 and the Canadian HPA Fresh Water Instant Filter Cleaner Version 1.0 Revision Date 2019.01.23 Print Date 2019.11.04 SECTION 1. IDENTIFICATION Product name : Fresh Water Instant Filter Cleaner Manufacturer or supplier's details Company : Arch Chemicals, Inc. 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States of America (USA) E-mail address : sds@lonza.com Emergency telephone number : In case of emergency call CHEMTREC US: 1-800-424-9300, CHEMTREC WORLD-WIDE: +1-703-527-3887. Recommended use of the chemical and restrictions on use Recommended use : Cleaning agent SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin irritation : Category 2 Serious eye damage : Category 1 Specific target organ toxicity - single exposure : Category 3 (Respiratory system) GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P312 Call a POISON CENTER/doctor if you feel unwell. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P403 + P233 Store in a well-ventilated place. Keep container tight- ly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Mixture Hazardous components Chemical name / Synonyms CAS-No. Concentration (% w/w) 2-Butoxyethanol 111-76-2 5 - 10 Poly(oxy-1,2-ethanediyl), .alpha.- (nonylphenyl)-.omega.-hydroxy- 9016-45-9 5 - 10 Etidronic acid 2809-21-4 3 - 5 Citric acid 77-92-9 1 - 3 SECTION 4. FIRST AID MEASURES If inhaled : IF INHALED: Remove individual to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops. In case of skin contact : IF ON SKIN: Immediately flush skin with plenty of water for 15 minutes. If clothing comes in contact with the product, the clothing should be removed immediately and laundered before re-use. Seek medical attention if irritation develops. In case of eye contact : IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical attention immediately. If swallowed : IF SWALLOWED: Call a physician immediately. DO NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person. Most important symptoms and ef- fects, both acute and delayed : None known. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use dry chemical, water fog, carbon dioxide (CO2), or foam. Specific hazards during firefighting : Material may be ignited if preheated to temperatures above the flash point in the presence of a source of ignition. Further information : Use water spray to cool unopened containers. In case of fire, use normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing appa- ratus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency proce- dures : Use the personal protective equipment recommended in Sec- tion 8 and a NIOSH approved self-contained breathing appa- ratus. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Utilize emergency response personal protection equipment prior to the start of any response. Evacuate all non-essential personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for contain- ment and cleaning up : Contain spillage, and then collect with non-combustible ab- sorbent material, (e.g. sand, earth, diatomaceous earth, ver- miculite) and place in container for disposal according to local / national regulations (see section 13). Do not flush into surface water or sanitary sewer system. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not take internally. Avoid contact with skin, eyes and cloth- ing. Upon contact with skin or eyes, wash off with water. Avoid breathing mist or vapor. Conditions for safe storage : Store in a cool, dry and well ventilated place. Isolate from incompatible materials. Avoid freezing. Materials to avoid : Refer to Section 10, "Incompatible Materials." SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissi- ble concentra- tion Basis 2-Butoxyethanol 111-76-2 TWA 20 ppm ACGIH REL 5 ppm 24 mg/m3 NIOSH/GUIDE PEL 50 ppm 240 mg/m3 OSHA_TRANS TWA 25 ppm 120 mg/m3 Z1A Biological occupational exposure limits Components CAS-No. Control parame- ters Biological specimen Sampling time Permissi- ble con- centration Basis 2-Butoxyethanol 111-76-2 Butoxya- Creatinine Sampling time: 200 mg/g ACGIH BEI cetic acid in urine End of shift. (BAA), with hy- drolysis Engineering measures : Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other rec- ommended exposure limit. Personal protective equipment Respiratory protection : Wear a NIOSH approved respirator if levels above the expo- sure limits are possible. A NIOSH approved air purifying respirator with organic vapor cartridge and N95 particulate filter. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the pub- lished limit. Hand protection Remarks : Avoid contact with skin. Impervious gloves Eye protection : Chemical resistant goggles must be worn. Face-shield Skin and body protection : Impervious clothing Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : no data available Odour : no data available Odour Threshold : no data available pH : 1.0 - 3.0 Melting point/freezing point : no data available Boiling point/boiling range : 215.1 °F / 101.7 °C Flash point : > 200.3 °F / 93.5 °C Evaporation rate : 1 Flammability (solid, gas) : Combustible above 93 deg. C / 200 deg. F. Flammability (liquids) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : 22.7 hPa Relative vapour density : 0.6 Relative density : 1.138 (68 °F / 20 °C) Density : Not applicable Bulk density : no data available Water solubility : soluble in cold water Partition coefficient: n-octanol/water : Not applicable Auto-ignition temperature : no data available Decomposition temperature : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reactions : Stable under normal conditions. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Strong acids Alkalis Hazardous decomposition products : Carbon oxides Nitrogen Aldehydes Ketones SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of expo- sure : Eyes Skin Ingestion Inhalation Acute toxicity Acute oral toxicity : LD50 (Rat): Believed to be > 3,700 mg/kg Acute dermal toxicity : LD50 (Rabbit): Believed to be > 1,700 mg/kg Acute toxicity (other routes of admin- istration) : Remarks: This product is corrosive to the eyes, moderately irritating to the skin and upon inhalation, may cause irritation to mucous membranes and respiratory tract. Skin corrosion/irritation Remarks: Moderate skin irritation Serious eye damage/eye irritation Result: Corrosive to eyes Respiratory or skin sensitisation Remarks: This material is not known or reported to be a skin or respiratory sensitizer. Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcino- gen by NTP. ACGIH Confirm mans ed animal carcinogen with unknown relevance to hu- 2-Butox yethanol 111-76-2 Repeated dose toxicity Remarks: Not known or reported to cause subchronic or chronic toxicity. Further information Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : EC50: Believed to be approximately 1,100 mg/l Method: Calculation method Persistence and degradability no data available Bioaccumulative potential Components: Citric acid: Partition coefficient: n-octanol/water : log Pow: -1.72 (20 °C) Method: OECD Test Guideline 107 Mobility in soil no data available Other adverse effects Ozone-Depletion Potential : Regulation: US. EPA Clean Air Act (CAA) Section 602 Ozone- Depleting Substances (40 CFR 82, Subpt. A, App A & B) Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : Practically non- toxic to fish and other aquatic organisms. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : If this product becomes a waste, it meets the criteria of a haz- ardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D002. As a hazardous liquid waste it must be disposed of in accord- ance with local, state and federal regulations. SECTION 14. TRANSPORT INFORMATION DOT : Not dangerous goods UN number : Not applicable Proper shipping name : Not applicable Transport hazard class : Not applicable Packing group : Not applicable TDG UN number : 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (1-Hydroxyethylidene-1,1-diphosphonic acid) Transport hazard class : 8 Packing group : III Labels : 8 Environmental hazards : no IATA UN number : 3265 Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (1-Hydroxyethylidene-1,1-diphosphonic acid) Transport hazard class : 8 Packing group : III Labels : 8 Environmental hazards : no IMDG UN number : 3265 Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (1-Hydroxyethylidene-1,1-diphosphonic acid) Transport hazard class : 8 Packing group : III Labels : 8 EmS Number 1 : F-A EmS Number 2 : S-B Environmental hazards : Marine pollutant: no ADR UN number : 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (1-Hydroxyethylidene-1,1-diphosphonic acid) Transport hazard class : 8 Packing group : III Classification Code : C3 Hazard Identification Number : 80 Labels : 8 Environmental hazards : no RID UN number : 3265 Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (1-Hydroxyethylidene-1,1-diphosphonic acid) Transport hazard class : 8 Packing group : III Classification Code : C3 Hazard Identification Number : 80 Labels : 8 Environmental hazards : no Special precautions for user : none Transport in bulk according to An- nex II of MARPOL 73/78 and the IBC Code : Not applicable SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 313 Components CAS-No. Concentration Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl)-.omega.-hydroxy- 9016-45-9 5 - 10 % Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): Components CAS-No. Concentration Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl)-.omega.-hydroxy- 9016-45-9 5 - 10 % This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Acci- dental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): Components CAS-No. Concentration 2-Butoxyethanol 111-76-2 5 - 10 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know Pennsylvania Right To Know Components CAS-No. 2-Butoxyethanol 111-76-2 Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl)-.omega.-hydroxy- 9016-45-9 Etidronic acid 2809-21-4 New Jersey Right To Know Components CAS-No. 2-Butoxyethanol 111-76-2 Poly(oxy-1,2-ethanediyl), .alpha.-(nonylphenyl)-.omega.-hydroxy- 9016-45-9 Etidronic acid 2809-21-4 Citric acid 77-92-9 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Canadian lists NPRI The components of this product are reported in the following inventories: TSCA : The components of this product are listed on the TSCA Inven- tory of Existing Chemical Substances. SECTION 16. OTHER INFORMATION Full text of other abbreviations ACGIH : US. ACGIH Threshold Limit Values ACGIH BEI : US. ACGIH. BEIs. Biological Exposure Indices NIOSH/GUIDE : US. NIOSH: Pocket Guide to Chemical Hazards OSHA_TRANS : US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Z1A : US. OSHA Table Z-1-A (29 CFR 1910.1000) AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materi- als; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substanc- es (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan- gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Ja- pan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Pro- tection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and De- velopment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumula- tive and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self- Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative 5 Revision Date : 2019.01.23 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Date format : yyyy/mm/dd US / EN